Analytical and Bioanalytical Electrochemistry is an international scientific journal, which is published online every 3 months (since 2009), every 2 months (since 2011) and monthly (since 2018) by Center of Excellence in Electrochemistry, University of Tehran
Analytical and Bioanalytical Electrochemistry
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2008-4226
12
3
2020
03
01
New Two-fold Amplified Electroanalytical Sensor for Determination of Xanthine in the Presences of Caffeine in Food Samples
289
300
EN
Niloofar
Dehdashtian
Seyed-Ahmad
Shahidi
Department of Food Science and Technology, Faculty of Agriculture and Food Science, Ayatollah Amoli Branch, Islamic Azad University, Amol, Iran
a.shahidi@iauamol.ac.ir
Majedeh
Bijad
Fast and sensitive response electrochemical sensor based on CoFe<sub>2</sub>O<sub>4</sub> nanoparticle and 1-buthyl-3-methyl imidazolium bromide room temperature ionic liquids carbon paste electrode (CoFe<sub>2</sub>O<sub>4</sub>/NP/ILs/CPE) is fabricated for the determination of Xanthine (Xt) in the presences of Caffeine in fish and fruit samples. In the first step, CoFe<sub>2</sub>O<sub>4</sub>/NP was characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD) and results showed synthesized nanoparticle with diameter between 26.92-29.22 nm. The electro-oxidation of Xt and Caffeine occurred at a potential about 0.7 V and 1.1 V, which was much better in comparison with bare carbon paste electrode in phosphate buffer (pH=6.0) at the surface of the (CoFe<sub>2</sub>O<sub>4</sub>/NP/ILs/CPE). Other electrochemical techniques were also investigated including cyclic voltammetry, differential pulse voltammetry (DPV) and chronoamperometry at CoFe<sub>2</sub>O<sub>4</sub>/NP/ILs/CPE. At optimized conditions for Xt and Caffeine analysis, DPV peak currents showed a wide linear dynamic ranging from 8.0 nM to 500 μM and detection limit for Xt was 3.0 nM and of course we obtained good dynamic range between 0.1 to 300 μM and good limit of detection 0.05 μM for caffeine. As a result, the proposed electrode could determine Xt in the presences of Caffeine in real samples with good selectivity and high sensitivity.
Xanthine,Caffeine,Carbon paste electrode,Fish samples,Fruit samples
https://www.abechem.com/article_38850.html
https://www.abechem.com/article_38850_2d77db3fc24d25ef9c91f4552020c3de.pdf
Analytical and Bioanalytical Electrochemistry is an international scientific journal, which is published online every 3 months (since 2009), every 2 months (since 2011) and monthly (since 2018) by Center of Excellence in Electrochemistry, University of Tehran
Analytical and Bioanalytical Electrochemistry
-
2008-4226
12
3
2020
03
01
A Review on the Semiconducting Behavior of Passive Films Formed on Mg Alloys by Mott–Schottky Analysis
301
317
EN
Arash
Fattah-alhosseini
Department of Materials Engineering, Bu-Ali Sina University, Hamedan 65178-38695, Iran
a.fattah@basu.ac.ir
Kazem
Babaei
babaeykazem@gmail.com
Mg alloys have a vast usage where weight reduction is really significant since they do the features really well for materials of ultra-light weight. However, Mg is inherently a reactive metal and its alloys generally possess quite weak corrosion resistance that widely restricts their technological usages, especially in some rough service conditions. Despite, many investigations on the passive and electrochemical properties of Mg alloys and their relation with the microstructure of these alloys, few reports have been devoted to investigate the semiconducting behavior of the formed oxide layers on these alloys. Mott–Schottky measurement is a major in-situ technique to analyze semiconductor behavior of passive layers. In this review, the semiconducting properties of formed passive layers on Mg alloys (AZ91D, AZ31B, AZ80, Mg-Y-Rare Earth-Zr alloys) by Mott–Schottky measurement has been assessed. Mott–Schottky measurements revealed the formed passive films on Mg alloys show mainly n-type behavior regardless the microstructure, pH, immersion time, and temperature of electrolyte.
Semiconducting behavior,Mg alloys,Passive film,Mott–Schottky (M–S) analysis
https://www.abechem.com/article_38851.html
https://www.abechem.com/article_38851_5870b7307027e465c927fa77e5420819.pdf
Analytical and Bioanalytical Electrochemistry is an international scientific journal, which is published online every 3 months (since 2009), every 2 months (since 2011) and monthly (since 2018) by Center of Excellence in Electrochemistry, University of Tehran
Analytical and Bioanalytical Electrochemistry
-
2008-4226
12
3
2020
03
01
Synthesis, Structure and Catalytic Performance of N4-Macrocycles of Fe III and Co II for Oxidation of Hydroquinone
318
328
EN
Vinod Kumar
Vashistha
Deepak Kumar
Das
Anubha
Yadav
Deepak
Saini
Anuj
Kumar
Department of Chemistry, Institute of Applied Science & Humanities, GLA University, Mathura, India
anuj.kumar@gla.ac.in
Macrocycles and p-benzoquinones (p-BQ) have been generally connected as potential co-synergist redox models in aerobic oxidation. To get insight for the synergist oxidation of hydroquinones (H<sub>2</sub>Q), thus, we synthesized and characterized dibenzotetraaza [14]annulene type macrocycles of Fe<sup>III</sup> and Co<sup>II</sup> metal ions and described by utilizing different examinations including molar conductance, IR, UV-Vis, mass and cyclic voltammetric measurements. The spectroscopic and computational studies proposed that the macrocycles have saddle shape distorted octahedral structure. These macrocycles demonstrated the reversible and quasi-reversible redox process pursued by Randles-Sevcik equation, demonstrating the adjustment of unusual oxidation conditions of metal ions. Further, the experimental consequences presented herein enlighten the catalytic activity of these macrocycles towards the oxidation of H<sub>2</sub>Q. The results indicated that in the absence of macrocycles, the molecular oxygen is inactive with H<sub>2</sub>Q but in presence of synthesized macrocycles H<sub>2</sub>Q initiates prompt oxidation with the production of H<sub>2</sub>O<sub>2</sub>. Moreover, Co<sup>II</sup> macrocycle was found to be an efficient catalyst for the oxidation of H<sub>2</sub>Q into corresponding benzoquinones.
Fe III/Co II Macrocycles,Template synthesis,CV and Catalytic Oxidation,Hydroquinones
https://www.abechem.com/article_38852.html
https://www.abechem.com/article_38852_cfb75058c3599ff2d231987b1f14ae3c.pdf
Analytical and Bioanalytical Electrochemistry is an international scientific journal, which is published online every 3 months (since 2009), every 2 months (since 2011) and monthly (since 2018) by Center of Excellence in Electrochemistry, University of Tehran
Analytical and Bioanalytical Electrochemistry
-
2008-4226
12
3
2020
03
01
Inhibitory Effect of Propolis against Corrosion Evaluated by Electrochemical Methods of Ti Grade 2 in Artificial Fluoride Saliva
329
344
EN
Faiza
Kakaa
Laboratory of Interaction Materials and Environment (LIME), Mohamed Seddik Ben Yahia University, Ouled Aissa BP 98, Jijel, Algeria
Mosbah
Ferkhi
Laboratory of Interaction Materials and Environment (LIME), Mohamed Seddik Ben Yahia University, Ouled Aissa BP 98, Jijel, Algeria
ferkhimosbah1@gmail.com
Mesbah
Lahouel
Laboratory of Molecular Toxicology, Department of Molecular and Cellular Biology, Faculty of Science, Mohamed Seddik Ben Yahia University, Ouled Aissa BP 98, Jijel, Algeria
The objective of this work was to demonstrate the effect of fluoride and propolis extract on the corrosion behavior of commercially pur titanium (cp-Ti grade 2) in artificial saliva. The inhibition studies were approved out on cp-Ti as dental implant in Fusayama-Meyer with the propolis extract using potentiodynamic polarization and Electrochemical Impedance Spectroscopy (EIS). Parameters, such as concentration of the inhibitor, time of immersion were varied and optimized. The results showed that either the NaF or the presence of propolis extract in medium saliva had a significant influence on the corrosion rate (I<sub>corr</sub>) and polarization resistance (R<sub>p</sub>): the Icorr value increased and R<sub>p</sub> decreased in medium containing fluoride, but the presence of propolis in media improved the corrosion resistance of this metal.
Propolis,Titanium grade 2,Inhibition,Fusayama-Meyer,electrochemical impedance spectroscopy
https://www.abechem.com/article_38853.html
https://www.abechem.com/article_38853_491e0557923f1a6c42b83180b524e574.pdf
Analytical and Bioanalytical Electrochemistry is an international scientific journal, which is published online every 3 months (since 2009), every 2 months (since 2011) and monthly (since 2018) by Center of Excellence in Electrochemistry, University of Tehran
Analytical and Bioanalytical Electrochemistry
-
2008-4226
12
3
2020
03
01
Analysis of Drug-Drug Interactions with Cyclic Voltammetry: An Overview of Relevant Theoretical Models and Recent Experimental Achievements
345
364
EN
Rubin
Gulaboski
Faculty of Medical Sciences, Goce Delcev University, Stip, Macedonia
rubin.gulaboski@ugd.edu.mk
Pavlinka
Kokoskarova
Faculty of Medical Sciences, Goce Delcev University, Stip, Macedonia
Sofija
Petkovska
In this review, we focus on cyclic voltammetry as a reliable electrochemical technique to study mechanisms, kinetics and thermodynamics of various types of drug-drug interactions. While we present and discuss six theoretical models relevant to analyze drug-drug (or drug-DNA) interactions, we also give hints about recent experimental achievements in this field. In addition, we provide the readers several sets of simulated voltammograms and data in tabular form, which can be used to recognize particular mechanism of drug-drug interactions in cyclic voltammetry. Moreover, we give hints to the voltammetric procedures that allow access to kinetics and thermodynamics parameters, which are relevant to various types of drug-drug interactions. The results we present in this work can be of big help to the scientists working in the field of pharmacy, pharmacology, medicinal chemistry and bio-electrochemistry.
Cyclic voltammetry,Thermodynamics of drug-drug interactions,Kinetics of drug-drug interactions,Stability constant of complexes,Electrode mechanisms
https://www.abechem.com/article_38854.html
https://www.abechem.com/article_38854_d41d8cd98f00b204e9800998ecf8427e.pdf
Analytical and Bioanalytical Electrochemistry is an international scientific journal, which is published online every 3 months (since 2009), every 2 months (since 2011) and monthly (since 2018) by Center of Excellence in Electrochemistry, University of Tehran
Analytical and Bioanalytical Electrochemistry
-
2008-4226
12
3
2020
03
01
Electrochemical Oxidation and Molecular Docking Studies of Leaves Extract of Lemon Verbena and Flowers Extract of Echium Amoenum: Green Antidotes for Treatment of Barbiturate Poisoning
365
375
EN
Ameneh
Amani
0000-0002-7474-3689
Department of Chemistry, University of Nahavand, Nahavand, Iran
amani.iran@gmail.com
Mahdi
Jamshidi
Department of Toxicology and Pharmacology, School of Pharmacy, Hamadan University of Medical Sciences, Hamadan, Iran
Electrochemical oxidation of leaves extract of lemon verbena and the flowers extract of echium amoenum have been studied in the absence and presence of barbituric acid and 1,3 dimethyl barbituric acidin aqueous solutions and biological pH, using cyclic voltammetry method. The results showed that the electrochemically generated compounds in leaves extract of lemon verbena and the flowers extract of echium amoenum, participate in the chemical reaction with barbituric acid and 1,3 dimethyl barbituric acid. Based on our results, leaves extractof lemon verbena and the flowers extract of echium amoenum have a high antioxidant activity in comparison with galic acid, salicylic acid and quercetin as standard antioxidants and simultaneous can be useful for the treatment of barbiturate poisoning before starting clinical treatments. The antioxidant activity of luteoline and verbascoside (as the main and natural compounds in lemon verbena) against some of the reactive oxygen species (ROS) generation enzymes, Cytochrome P450 3A4 (4D75), Myeloperoxidase (1DNW) and Thyosine (3nm8) has been performed through molecular docking studies. The results indicated that these natural compounds bound exclusively to the binding site of ROS generation enzymes and has a remarkable role in suppressing the destructive effects of oxidative stress in the biological system of the human body.
Herb-drug interaction,Barbiturate poisoning,Electrochemical oxidation,Antioxidant Activity
https://www.abechem.com/article_38855.html
https://www.abechem.com/article_38855_0456e7fa6fb507bf1bc69965b33a094f.pdf
Analytical and Bioanalytical Electrochemistry is an international scientific journal, which is published online every 3 months (since 2009), every 2 months (since 2011) and monthly (since 2018) by Center of Excellence in Electrochemistry, University of Tehran
Analytical and Bioanalytical Electrochemistry
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2008-4226
12
3
2020
03
01
Determination of Strontium Ion in Depilatory Powder, Toothpaste, and Raticide Samples using a Novel and Highly Sensitive Potentiometric Sensor Coupled with a Central Composite Design
376
391
EN
Esmat
Shojaeia
Mahboubeh
Masrournia
Department of Chemistry, Faculty of Sciences, Mashhad Branch, Islamic Azad University P.O. Box 91735-413, Mashhad, Islamic Republic of Iran
masrournia@yahoo.com
Ali
Beyramabadi
Hossein
Behmadi
The strontium ion, in water-soluble forms, is one of the major pollutant in drinking water. Therefore, a simple, rapid, selective, and sensitive potentiometric carbon paste electrode was developed to measure strontium ion in real samples with complex matrices. To prepare the potentiometric sensor, a synthetic ligand ((E)-4-(((2-amino-4-chlorophenyl)imino)methyl)-5-(hydroxymethyl)-2-methyl pyridine-3-ol) as an efficient ionophore and an ionic liquid (1-Butyl-3-methylimidazolium hexafluorophosphate) as a suitable binder were dispersed in a mixture of graphite powder and graphene oxide. The composition of the sensor was optimized using a central composite design (full factorial) to reduce the number of experimental runs and investigate interactions between effective factors. The proposed sensor showed a Nernstian behavior in the linear concentration range of 1×10<sup>-8</sup> to 1.0×10<sup>-1</sup> M with a low detection limit (1.59×10<sup>−9</sup> M) and suitable relative standard division (1.01 %). The proposed sensor can be well applied in the pH range of 3.00-9.50 for the analyte determination. Moreover, the proposed electrode as an indicator electrode was successfully used to measure the Sr(II) concentration in the depilatory powder, toothpaste, and raticide samples.
Strontium determination,Potentiometric sensor,Central composite design,Depilatory powder sample,Toothpaste sample,Raticide sample
https://www.abechem.com/article_38856.html
https://www.abechem.com/article_38856_353753160d5d975897de98453a948ac4.pdf
Analytical and Bioanalytical Electrochemistry is an international scientific journal, which is published online every 3 months (since 2009), every 2 months (since 2011) and monthly (since 2018) by Center of Excellence in Electrochemistry, University of Tehran
Analytical and Bioanalytical Electrochemistry
-
2008-4226
12
3
2020
03
01
Electrochemical Determination of Neonicotinoid Insecticide Clothianidin by Nanomaterial based Disposable Electrode
392
401
EN
Baha
Öndeş
Adnan Menderes University, Faculty of Arts and Sciences, Department of Chemistry, 09010 Aydın, Turkey
Mihrican
Muti
Adnan Menderes University, Faculty of Arts and Sciences, Department of Chemistry, 09010 Aydın, Turkey
mihricanmuti@gmail.com
Disposable, selective and low-cost carbon nanotube modified electrodes were fabricated for the electrochemical detection of neonicotinoid insecticide, Clothianidin (CLT). Almost 2 folds’ increase at Clothianidin reduction signal was obtained by using single-walled carbon nanotube modified electrodes (SWCNT-PGE) compared to unmodified electrodes. These nanomaterials modified electrodes developed in this study will enable simple, rapid and inexpensive identification of the neonicotinoid insecticides, Clothianidin and it is hoped that this technique developed by using these nanosensors will be an alternative to the expensive and time consuming chromatographic techniques with its advantages of adapting to the sensor chip technology for the routine analysis of agricultural products.
Voltammetry,Modified sensor,Disposable electrode,Carbon Nanotube,Clothianidin
https://www.abechem.com/article_38857.html
https://www.abechem.com/article_38857_4287613485094257fd61af1f6357ec79.pdf
Analytical and Bioanalytical Electrochemistry is an international scientific journal, which is published online every 3 months (since 2009), every 2 months (since 2011) and monthly (since 2018) by Center of Excellence in Electrochemistry, University of Tehran
Analytical and Bioanalytical Electrochemistry
-
2008-4226
12
3
2020
03
01
Development of A New Electrochemical Sensor based on Zr-MOF/MIP for Sensitive Diclofenac Determination
402
414
EN
Maryam
Malekzadeh
Department of Chemistry, Payame Noor University, P.O. Box 19395-4697 Tehran, Iran
Alireza
Mohadesi
Department of Chemistry, Payame Noor University, P.O. Box 19395-4697 Tehran, Iran
mohadesi@pnu.ac.ir
Mohammad Ali
Karimi
Mehdi
Ranjbar
Pharmaceutics Research Center, Institute of Neuropharmacology, Kerman University of Medical Sciences, Kerman, Iran
mehdi.ranjbar@kmu.ac
In this study, a new molecularly imprinted polymer with nanoporous material of zirconium metal-organic frameworks (Zr-MOF/MIP) for diclofenac (DFC) measurement is presented. The Zr-MOF/MIP was prepared by electropolymerization method, the Zr-MOFs were used to increase electrode surface and the DFC and para- aminobenzoic acid (pABA) were used as template and functional monomer, respectively. Zr--MOFs was characterized by using X-ray powder diffraction (XRD), scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FTIR). The electrochemical performance was investigated using cyclic voltammetry (CV) and differential pulse voltammetry (DPV). Sensor response was evaluated by comparing the electrochemical response of Zr-MOF/MIP, with that of non- Imprinted polymer (NIP), in a 2.0 mM potassium ferrocyanide solution containing 0.2 mM sodium sulfate as probe solution. Measurements were carried out in the potential range of -0.6 to +1.0 V with scan rate of 50 mV/s. The calibration curve of diclofenac was linear in the concentration range of 6.5 μM to 1.5×10<sup>+3</sup> μM. Detection limit was obtained 0.1 μM and relative standard deviation of several (n=7) replicate measurements for 1.0 mM DFC concentration has obtained 1.8%. Furthermore, favorable sensitivity, selectivity, good reproducibility and long-term stability, was obtained in the experiment and the proposed electrode was applied for the determination of DFC in pharmaceutical commercial sample with satisfactory results.
Metal organic framework,Molecularly imprinted polymer,Electropolymerization,Diclofenac
https://www.abechem.com/article_38858.html
https://www.abechem.com/article_38858_93084b9086f3d0f549709a6e5781b2cb.pdf
Analytical and Bioanalytical Electrochemistry is an international scientific journal, which is published online every 3 months (since 2009), every 2 months (since 2011) and monthly (since 2018) by Center of Excellence in Electrochemistry, University of Tehran
Analytical and Bioanalytical Electrochemistry
-
2008-4226
12
3
2020
03
01
Synthesis, Antimicrobial and Electrochemical Studies of Four Substituted Isatin Derivatives at a Glassy Carbon Electrode
415
424
EN
K. S.
Ashoka
G. P.
Mamatha
Department of Pharmaceutical Chemistry, Post Graduate Centre, Kadur-577548, Karnataka, India
mamatha_gp2005@rediffmail.com
H. M.
Santhosh
Isatins, derivatives of indole, represent important class of compounds belonging to nitrogen heterocycles. These compounds comprise synthetically vital substrates that are used as precursors for drug synthesis and raw materials for heterocycles etc. Research in this group of compounds has engrossed interest among scientific community in recent and past as Isatins are known to possess immense biological activities. Present work delineates synthesis, characterization, electrochemical and antimicrobial studies of four substituted derivatives of isatin derivatives. The cyclic voltammetric studies of all the analytes showed that four derivatives have better electro catalytic activity towards the analytes at glassy carbon electrode. These synthesized isatin derivatives were screened for their antimicrobial activity against Gram-negative bacteria (Escherichia coli and Staphylococcus aureus) and fungi such as Candida albicans and Penicillin chrysogenum, and found to possess considerable antimicrobial activity suggesting their effectiveness in developing antibiotics and novel drugs.
Cyclic voltammetry,Glassy carbon electrode,Antimicrobial activity,Isatin derivatives
https://www.abechem.com/article_38859.html
https://www.abechem.com/article_38859_6f2acce023904cae089c8d9f641fa8cc.pdf