Poly(Niacin) Based Carbon Nanotube Sensor for the Sensitive and Selective Voltammetric Detection of Vanillin with Caffeine

Authors

1 Department of Chemistry, FMKMC College, Madikeri, Mangalore University Constituent College, Karnataka, India

2 School of Pharmacy, Management and Science University, Malaysia

Abstract

In the current work, a novel sensor was developed for the analysis of Vanillin (VN) by electrochemical polymerization of Niacin over the surface of carbon nanotube paste electrode. The features of electrode surface was studied using Field Emission Scanning Electron Microscopy (FE‒SEM) images. Sweep rate variation study was conducted in the optimum pH (pH 7.0) for the evaluation of number of electrons involved in the electrochemical reaction and to investigate the mode of mass transfer phenomena. This investigation reveals that the electrode undergoes adsorption controlled mass transfer process. Based on the data obtained from the measurements the oxidation mechanism of VN was proposed. The prepared sensor was also applied for the simultaneous detection of VN and Caffeine (CF). Quantitative determination of VN was accomplished by cyclic voltammetric (CV) method. The corresponding value of limit of detection (LOD) and limit of quantification (LOQ) of VN was found to be 10.1×10-7 M and 3.3×10-6 M, respectively. In addition, the applicability of the proposed method was checked with the detection of VN in real sample with good recovery data.

Keywords

References

[1] N. J. Walton, M. J. Mayer, and A. Narbad, Phytochemistry 63 (2003) 505.
[2] G. Jin, Y. Feng, S. Shuang, and L. Yun, Adv. Mat. Res. 236 (2011) 2725.
[3] N. W. Krzysztof, T. P. Violeta, and L. O. Sandy, Food Chem. 101 (2006) 1059.
[4] A. K. Sinha, U. K. Sharma, and N. Sharma, Int. J. Food Sci. Nutr. 59 (2008) 299.
[5] S. Yan, H. Chao, L. Bin, L. Zhengfeng, Z. Xiujin, W. Chengjun, and Z. Zhenou, J Dairy Sci. 97 (2014) 679.
[6] D. Farthing, D. Sica, C. Abernathy, I. Fakhry, J. D. Roberts, D. J. Abraham, and P. Swerdlow, J. Chromatogr B Biomed. Sci. Appl. 726 (1999) 303.
[7] P. L. Teissedre, and A. L. Waterhouse, J Agr. Food Chem. 48 (2000) 3801.
[8] P. Deng, Z. Xu, R. Zeng, and C. Ding, Food Chem. 180 (2015) 156.
[9] L. Cheng, and Z. Chang-Li, Asian J. Chem. 26 (2014) 3121.
[10] Y. Aydin, A. Nurcan, Y. Yavuz, C. Metin, and S. Zuhre, Electroanalysis 30 (2018) 1.
[11] Z. Jin, X. Haixiong, Y. Tingyu, J. Lu, L. Xuehua, Z. Yinghui, S. Liping, Z. Lingwen, and H. Zhixu, PLoS ONE. 13 (2018) e0194010.
[12] A. K. Sinha, S. C. Verma, and U. K. Sharma, J Sep. Sci. 30 (2007) 5.
[13] L. Yong-Hong, S. Zhi-Hao, and Z. Pu, Chromatographia 60 (2004) 709.
[14] Y. Ni, G. Zhang, and S. Kokot, Food Chem. 89 (2005) 465.
[15] M. Timotheou-Potamia, and A. C. Calokerinos, Talanta 71 (2007) 208.
[16] M. Bononi, G. Quaglia, and F. Tateo, J Agr. Food Chem. 63 (2015) 4777.
[17] S. Minematsu, G. S. Xuan, and X. Z. Wu, J Environ. Sci. (China) 25 (2013) 8.
[18] K. L. Goodner, P. Jella, and R. L. Rouseff, J Agr. Food Chem. 48 (2000) 2882.
[19] M. Takahashi, S. Sakamaki, and A. Fujita, Biosci. Biotechnol. Biochem. 77 (2013) 595.
[20] F. Bettazzi, I. Palchetti, S. Sisalli, and M. Mascini, Anal. Chim. Acta. 555 (2006) 134.
[21] D. Y. Zheng, C. G. Hu, T. Gan, X. P. Dang, and S. S. Hu, Sens. Actuators B Chem. 148 (2010) 247.
[22] M. Sivakumar, M. Sakthivel, and S. M. Chen, J Colloid Interface Sci. 490 (2017) 719.
[23] L. Huang, K. Hou, X. Jia, H. Pan, and M. Du, Mater. Sci. Eng. C. 38 (2014) 39.
[24] T. C. Tugba, and U. Demet, Electroanalysis 31 (2019) 1.
[25] S. A. Hoshyar, A. A. Abdullah, T. P. Pınar, Y. Yavuz, and S. Zühre, Talanta 170 (2017) 384.
[26] H. Filik, A. A. Avan, and Y. Mümin, Food Anal. Methods. 10 (2017) 31.
[27] T. R. Silva, D. Brondani, E. Zapp, and I. C. Vieira, Electroanalysis 27 (2015) 465.
[28] P. Prabhu, R. S. Babu and S. S. Narayanan, J Mater. Sci. Mater. Electron. 30 (2019) 9955.
[29] N. P. Shetti, S. D. Bukkitgar, K. R. Reddy, C. V. Reddy, and T. M. Aminabhavi, Biosens. Bioelectron. 141 (2019) 111417.
[30] I. Becerik, and F. Kadirgan, Turk. J Chem. 25 (2001) 373.
[31] Ö. Çolak, and F. Arslan, Turk. J Chem. 39 (2015) 84.
[32] J. G. Manjunatha, B. E. Kumara Swamy, M. T. Shreenivas, and G. P. Mamatha, Anal. Bioanal Electrochem. 4 (2012) 225.
[33] J. G. Manjunatha, M. Deraman, N. H. Basri, N. S. M. Nor, I. A. Talib, and N. Ataollahi, C R Chimie. 17 (2014) 465.
[34] C. Raril, and J. G. Manjunatha, Anal. Bioanal. Electrochem. 10 (2018) 488.
[35] A. M. Mona, A. A. Shimaa, N. S. Nahla, and E. B. Craig, Electroanalysis 29 (2017) 1.
[36] U. K. Şükriye, and C. K. Çağrı, Turk. J. Chem. 42 (2018) 291.
[37] G. Tigari, J. G. Manjunatha, C. Raril, and N. Hareesha, Chemistry Select 4 (2019) 2168.
[38] P. A. Pushpanjali, and J. G. Manjunatha, J. Mater. Environ. Sci. 10 (2019) 939.
[39] J. R. B. Rodriguez, A. Costa Garcia, and P. T. Blanco, Electrochim. Acta. 34 (1989) 957.
[40] N. S. Prinith, and J. G. Manjunatha, Mater. Sci. Energy Technol. 2 (2019) 408.
[41] L. Yuxia, L. Yunzhen, L. Huan, Z. Cuizong, and P. Jinyun, Int. J. Electrochem. Sci. 10 (2015) 4129.
[42] P. A. Pushpanjali, J. G. Manjunatha, and M. T. Shreenivas, Chemistry Select 4 (2019) 13427.
[43] P. A. Pushpanjali, and J. G. Manjunatha, Phys. Chem. Res. 7 (2019) 813.
[44] B. M. Amrutha, J. G. Manjunatha, A. S. Bhatt, C. Raril, and P. A. Pushpanjali, Phys. Chem. Res. 7 (2019) 523.
[45] N. P. Shetti, and D. S. Nayak, Can. J. Chem. 95 (2017) 553.
[46] J. G. Manjunatha, Sens. Biosens. Res. 16 (2017) 79.
[47] L. Agüí, J. E. López-Guzmán, A. González-Cortés, P. Yáñez-Sedeño, and J. M. Pingarrón, Anal. Chim. Acta. 385 (1999) 241.
[48] M. Luque, E. Luque-Pérez, A. Ríos, and M. Valcárcel, Anal. Chim.
[49] J. L. Hardcastle, C. J. Paterson, and R. G. Compton, Electroanalysis 13 (2001) 899.
[50] B. K. Chethana, S. Basavanna, and Y. A. Naik, J Chem. Pharm. Res. 4 (2012) 538.
Analytical and Bioanalytical Electrochemistry
Volume 12, Issue 4
April 2020
Pages 553-568

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History

  • Receive Date: 20 March 2020
  • Revise Date: 13 April 2020
  • Accept Date: 17 April 2020

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