Analytical and Bioanalytical Electrochemistry

Analytical and Bioanalytical Electrochemistry

Simultaneous Determination of p-Benzoquinone and Resorcinol at Reduced Graphene Oxide Modified Glassy Carbon Electrode

Document Type : Original Article

Authors
Eleilde De Sousa Oliveira
Aldalea Lopes Brandes Marques
Ismael Carlos Braga Alves
Edmar Pereira Marques
José Ribamar Nascimento dos Santos
Raquel Bezerra Santos Sawczuk
Lorena Carvalho Martiniano de Azevedo
Janyeid Karla Castro Sousa
Nucleus for Studies in Petroleum and Energy (NEPE): LPQA & LAPQAP, Department of Chemical Technology, Federal University of Maranhão (UFMA), São Luís - MA, Brazil
10.22034/abec.2024.717549
Abstract
In this work we report the development of an electrochemical sensor based on a modified glassy carbon electrode (GCE) modified with reduced graphene oxide (rGO) for simultaneous determination of p-benzoquinone (BQ) and resorcinol (RS) in soil and water samples of gas stations, using the electrochemical techniques of cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and square wave voltammetry (SWV). The sensor modification was carried out by drop casting, a 10 µL aliquot of the rGO suspension was dropped onto the surface of the GCE. The sensor showed a linear response for both analytes through SWV from 20 µM up to 100 µM. Good results of sensitivity, limit of detection (LOD), and quantification (LOQ) were obtained for BQ (0.03 µA µM−1, 0.37 µM, and 1.23 µM) and RS (0.07 µA µM−1, 0.81 µM, and 2.71 µM), respectively. The method was tested in environmental samples (soil and water) through spike and recovery procedure (recovery > 99%), with precision (RSD) of 0.10% (BQ) and 0.36% (RS).
Keywords
Benzene derivatives
Environmental samples
Reduced graphene oxide
Electrochemical determination
Voltammetry
Subjects
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Analytical and Bioanalytical Electrochemistry
Volume 16, Issue 10
October 2024
Pages 910-927

  • Receive Date 19 June 2024
  • Revise Date 18 October 2024
  • Accept Date 24 October 2024