Polymer-Graphite Composite Electrodes for Methanol Oxidation in Microbial Fuel Cells: Development and Performance Analysis

Haddouchy, Hassan; Loughmari, Saliha; Tahiri, Youness; Oukbab, Mustapha; Oubaouz, Mohamed; Zehra Hamidi, Fatim; Smaini, Imane; El Bouadili, Abdelaziz; Chtaini, Abdelilah; EL Qouatli, Salah Eddine

doi:10.22034/abec.2025.723271

Polymer-Graphite Composite Electrodes for Methanol Oxidation in Microbial Fuel Cells: Development and Performance Analysis

Document Type : Original Article

Authors

Hassan Haddouchy ¹

Saliha Loughmari ²

Youness Tahiri ³

Mustapha Oukbab ³

Mohamed Oubaouz ³

Fatim Zehra Hamidi ¹

Imane Smaini ³

Abdelaziz El Bouadili ²

Abdelilah Chtaini ³

Salah Eddine EL Qouatli ¹

¹ Physical Chemistry Environment and Material, Moulay Ismail University, Faculty of Sciences and Technologies, Boutalamine 52000, Errachidia, Morocco

² Laboratory of Industrial and Surface Engineering, Applied Chemistry and Environmental Sciences Team, Sultan Moulay Slimane University, Faculty of Sciences and Technology, Mghilla Campus, P.B 523, 23000, Beni-Mellal, Morocco

³ Electrochemistry and Molecular Inorganic Materials Team, Faculty of Sciences and Technology, Sultan Moulay Slimane University, Mghilla Campus, BP 523, 23000, Beni-Mellal, Morocco

10.22034/abec.2025.723271

Abstract

This work focuses on the study of the biocatalyzed electrolytic oxidation of methanol by bacteria in a 1M Na2SO4 solution, using a carbon paste electrode modified with poly(1,4-myrcene-co-styrene) polymer. The electrode was obtained by immersing the carbon paste electrode in the polymer for 3 hours, ensuring that the surface of the CPE was uniformly covered with a polymer film. The prepared electrode demonstrated high activity in methanol oxidation. We investigated the impact of various parameters such as scan rate, cycles, and the duration of electrode contact with bacteria. Analysis of the electrode morphology through optical microscopy revealed that the polymer was uniformly deposited on the surface. Subsequently, we studied the electrode behavior using voltammetry techniques, employing the Volta Lab PGZ100 potentiostat. The results of these techniques highlighted the existence of a catalytic effect

Keywords

Fuel cells

Methanol

Cyclic voltammetry

Optical microscopy

Pseudomonas

Subjects