Analytical and Bioanalytical Electrochemistry

Analytical and Bioanalytical Electrochemistry

Synthesis, Characterization, and Electrochemical Studies of Ni Complexes

Document Type : Review

Authors
1 Department of Chemistry, GLA University, Mathura, Uttar Pradesh-281406, India
2 Department of Chemistry, Faculty of Science, Agriculture and Engineering, University of Zululand, P/Bag X1001, KwaDlangezwa, 3886, South Africa
3 Department of Chemistry, University of Lucknow, Lucknow, UP-226007, India
4 Department of Chemistry, Shyam Lal College, University of Delhi, Delhi-110032, India
Abstract
Nickel-based complexes are increasingly studied due to their promising roles in medicine, catalysis, and energy storage. This review offers an in-depth survey of recent progress in the synthesis of nickel complexes, with emphasis on methods involving both organic and inorganic ligands. The influence of ligand type on the stability, geometry, and electronic characteristics of these complexes is discussed in detail. Key analytical techniques, such as UV-Vis spectroscopy, FTIR, NMR, and X-ray diffraction, are highlighted for their importance in characterizing the structure and composition of nickel complexes. The review also examines the electrochemical properties of these compounds, focusing on their redox behavior and potential applications as catalysts in energy-related processes. Critical factors influencing the performance and reactivity of nickel complexes, including ligand environment, nickel oxidation state, and coordination geometry, are identified and analyzed. This article aims to provide valuable insights for researchers focusing on the design, characterization, and diverse applications of nickel-containing complexes in various scientific fields.
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Volume 17, Issue 8
August 2025
Pages 721-746

  • Receive Date 16 July 2025
  • Revise Date 30 September 2025
  • Accept Date 30 October 2026