Determination of Copper Content of Human Blood Plasma by an Ion Selective Electrode based on a New Copper-Selectophore

Authors

Center of Excellence in Electrochemistry, School of Chemistry, University of Tehran, Tehran, Iran

Abstract

A new selectophore was introduced for Cu2+ ions. Spectroscopic studies showed a selectivity of a new organic compound (L) toward copper ions and several transitional metal ions. Hence, L was utilized in designing several ion selective electrodes for these cations. In practice, Cu2+ ion selective electrode behaved Nernstian (slope of 27.95±0.3 mV decade-1) over a wide linear range of 1.0×10-6-1.0×10-2 mol L-1. Optimum performance of the indicator electrode was observed by a membrane containing 7% selectophore, 2% sodium tetraphenyl borate (NaTPB) as an ionic additive, 61% nitrobenzene (NB) as solvent mediator and 30% polyvinyl chloride (PVC). The sensor showed a short response time of about 20 s and an acceptable life time, the potentiometric response is independent on the pH of the solution in the range of 3.5-7. The optimized copper sensor was used for analysis of copper content of some blood plasma samples. The obtained results were in good agreements with ICP-OES method.

Keywords

References

[1] H.A. Zamani, M. Nekoei, M. Mohammadhosseini, and M.R. Ganjali, Mater. Sci. Eng. C 30 (2010) 480.
[2] F. Faridbod, M.R. Ganjali, B. Larijani, P. Norouzi, S. Riahi, and F.S. Mirnaghi, Sensors 7 (2007) 3119.
[3] H.A. Zamani, G. Rajabzadeh, and M.R. Ganjali, Talanta 72 (2007) 1093.
[4] M.R. Ganjali, M. Qomi, A. Daftari, P. Norouzi, M. Salavati-Niasari, and M. Rabbani, Sens. Actuators B 98 (2004) 92.
[5] M. Javanbakht, A. Shabani-Kia, M.R. Darvich, M.R. Ganjali, and M. Shamsipur, Anal Chim. Acta 408 (2000) 75.
[6] H.A. Zamani, A. Imani, A. Arvinfar, F. Rahimi, M.R. Ganjali, F. Faridbod, and S. Meghdadi, Mater. Sci. Eng. C 31 (2011) 588.
[7] M.R. Ganjali, H.A. Zamani, P. Norouzi, M. Adib, M. Rezapour, M. Aceedy, Bull. Korean Chem. Soc. 26 (2005) 579.
[8] M.R. Ganjali, H.A. Zamani, P. Norouzi, M. Adib, and M. Accedy, Acta Chim. Slov. 52 (2005) 309.
[9] H.A. Zamani, M.R. Ganjali, P. Norouzi, and S. Meghdadi, Anal. Lett. 41 (2008) 902.
[10] M.R. Ganjali, A. Daftari, M. Rezapour, T. Puorsaberi, and S. Haghgoo, Talanta 59 (2003) 613.
[11] M.R. Ganjali, A. Daftari, P. Nourozi, and M. Salavati-Niasari, Anal. Lett. 36 (2003) 1511.
[12] M. Shamsipur, S. Rouhani, M.R. Ganjali, H. Eshghi, and H. Sharghi, Microchem. J. 63 (1999) 202.
[13] H.A. Zamani, J. Abedini-Torghabeh, and M.R. Ganjali, Electroanalysis 18 (2006) 888.
[14] M.R. Ganjali, A. Roubollahi, A.R. Mardan, M. Hamzeloo, A. Mogimi, and M. Shamsipur, Microchem. J. 60 (1998) 122.
[15] M.R. Ganjali, P. Norouzi, M. Adib, and A. Ahmadalinezhad, Anal. Lett. 39 (2006) 1075.
[16] M.R. Ganjali, Z. Memari, F. Faridbod, and P. Norouzi, Int. J. Electrochem. Sci. 3 (2008) 1169.
[17] H.A. Zamani, G. Rajabzadeh, M.R. Ganjali, and P. Norouzi, Anal. Chim. Acta 598 (2007) 51.
[18] H.A. Zamani, M.R. Ganjali, and M. Adib, Sens. Actuators B 120 (2007) 545.
[19] M.R. Ganjali, R. Kiani-Anbouhi, M. Shamsipur, T. Poursaberi, M. Salavati-Niasari, Z. Talebpour, and M. Emami, Electroanalysis 16 (2004) 1002.
[20] M.R. Ganjali, M.R. Pourjavid, M. Rezapour, and S. Haghgoo, Sens. Actuators B 89 (2003) 21.
[21] I. Scheiber, R. Dringen, and J.F.B. Mercer, "Copper: Effects of Deficiency and Overload". In Sigel, Astrid; Sigel, Helmut; Sigel, Roland K.O. (Eds.). Interrelations between Essential Metal Ions and Human Diseases. Metal Ions in Life Sciences; Springer 13 (2013) pp. 359.
[22] M. Bost, S. Houdart, M. Oberli, E. Kalonji, J. Huneau, and I. Margaritis, J. Trace Elements in Medicine and Biology 35 (2016) 107.
[23] J. Karthikeyan, P.P. Naik, and A.N. Shetty, Environ. Monit. Assess. 176 (2010) 419.
[24] J. Škrlíková, V. Andruch, I.S. Balogh, L. Kocúrová, L. Nagy, and Y. Baze, Microchem. J. 99 (2011) 40.
[25] T. Leelasattarathkul, S. Liawruangrath, M. Rayanakorn, W. Oungpipat, and B. Liawruangrath, Talanta 70 (2006) 656.
[26] S. Abbasi, H. Khani, and R. Tabaraki, Food Chem. 123 (2010) 507.
[27] B. Soleiman, and Z. Razieh, J. Braz. Chem. Soc. 23 (2012) 1166.
[28] T. Rohani, and M.A. Taher, J. AOAC Int. 91 (2008) 1478.
[29] B.C. Janegitz, L.H. Marcolino-Junior, S.P. Campana-Filho, R.C. Faria, and O. Fatibello-Filho, Sens. Actuators B 142 (2009) 260.
[30] M.R. Ganjali, Z. Memari, F. Faridbod, R. Dinarvand, P. Norouzi, Electroanalysis 20 (2008) 2663.
[31] M.R. Ganjali, P. Norouzi, F.S. Mirnaghi, S. Riahi, and F. Faridbod, IEEE Sens. J. 7 (2007) 1138.
[32] H.A. Zamani, F. Malekzadegan, and M.R. Ganjali, Anal. Chim. Acta 555 (2006) 336.
[33] M.R. Ganjali, S. Rasoolipour, M. Rezapour, P. Norouzi, A. Tajarodi, and Y. Hanifehpour, Electroanalysis 17 (2005) 1534.
[34] M.R. Ganjali, M. Rahimi, B. Maddah, A. Moghimi, S. Borhany, Anal. Sci. 20 (2004) 1427.
[35] M.R. Ganjali, P. Norouzi, F. Faridbod, S. Riahi, J. Ravanshad, J. Tashkhourian, M. Salavati-Niasari, and M. Javaheri, IEEE Sens. J. 7 (2007) 544.
[36] M.R. Ganjali, P. Norouzi, A. Atrian, F. Faridbod, S. Meghdadi, and M. Giahi, Mater. Sci. Eng. C 29 (2009) 205.
[37] H.A. Zamani, M.R. Ganjali, P. Norouzi, and M. Adib, Mater. Sci. Eng. C 28 (2008) 157.
[38] M.R. Ganjali, M. Rezapour, M.R. Pourjavid, S. Haghgoo, Anal. Sci. 20 (2004) 1007.
[39] M.R. Ganjali, M. Tahami, M. Shamsipur, T. Poursaberi, S. Haghgoo, and M. Hosseini, Electroanalysis 15 (2003) 1038.
[40] M.R. Ganjali, L. Naji, T. Poursaberi, M. Shamsipur, S. Haghgoo, Anal. Chim. Acta 475 (2003) 59.
[41] M. Shamsipur, M. Yousefi, M. Hosseini, and M.R. Ganjali, Anal. Lett. 34 (2001) 2249.
[42] H.A. Zamani, M.R. Ganjali, P. Norouzi, and M. Adib, Sensor Lett. 5 (2007) 522.
[43] H.A. Zamani, M.T. Hamed-Mosavian, E. Hamidfar, M.R. Ganjali, and P. Norouzi, Mater. Sci. Eng. C 28 (2008) 1551.
[44] H.A. Zamani, G. Rajabzadeh, and M.R. Ganjali, J. Brazil. Chem. Soc. 17 (2006) 1297.
[45] H.A. Zamani, G. Rajabzadeh, M. Masrornia, A. Dejbord, M.R. Ganjali, and N. Seifi, Desalination 249 (2009) 560.
[46] M.R. Ganjali, R. Nemati, F. Faridbod, P. Norouzi, and F. Darviche, Int. J. Electrochem. Sci. 3 (2008) 1288.
[47] H.A. Zamani, M.R. Ganjali, and M.J. Pooyamanesh, J. Brazil Chem. Soc. 17 (2006) 149.
[48] H.A. Zamani, M.R. Ganjali, P. Norouzi, and S. Meghdadi, J. Appl. Electrochem. 37 (2007) 853.
[49] H.A. Zamani, M. Rohani, A. Zangeneh-Asadabadi, M.S. Zabihi, M.R. Ganjali, and M. Salavati-Niasari, Mater. Sci. Eng. C 30 (2010) 917.
[50] L. Yu, I. W. Liou, S. W. Biggins, M. Yeh, F. Jalikis, L. Chan, and J. Burkhead, Hepatol. Commun. 26 (2019) 1159.
Analytical and Bioanalytical Electrochemistry
Volume 12, Issue 6
June 2020
Pages 881-892

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History

  • Receive Date: 20 January 2020
  • Revise Date: 17 May 2020
  • Accept Date: 23 May 2020

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